Nozoe Soichiro, Kinoshita Nobuaki, Matsuda Masaki
J Nanosci Nanotechnol. 2016 Apr;16(4):3398-401. doi: 10.1166/jnn.2016.12287.
By using the short-time electrocrystallization technique, phthalocyanine (Pc)-based Mott insulator Co(Pc)(CN)2 . 2CHCl3 nanocrystals were fabricated and applied to organic light-emiting diodes (OLEDs). The fabricated device having the configuration ITO/Co(Pc)(CN)2 . 2CHCl3/Alq3/Al, in which ITO is indium-tin oxide and Alq3 is tris(8-hydroxyquinolinato)aluminum, showed clear emission from Alq3, suggesting the Mott insulator Co(Pc)(CN)2 . 2CHCl3 can work as useful hole-injection and transport material in OLEDs.
通过使用短时电结晶技术，制备了基于酞菁（Pc）的莫特绝缘体Co（Pc）（CN）₂·2CHCl₃纳米晶体，并将其应用于有机发光二极管（OLED）。所制备的器件结构为ITO/Co（Pc）（CN）₂·2CHCl₃/Alq₃/Al，其中ITO是氧化铟锡，Alq₃是三（8-羟基喹啉）铝，该器件显示出Alq₃的清晰发光，这表明莫特绝缘体Co（Pc）（CN）₂·2CHCl₃可作为OLED中有用的空穴注入和传输材料。
