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含碳酸盐电解质的离子液体对碳电极的离子传导性能研究

Study on Ion-Conducting Properties of Ionic Liquid Containing Carbonate Electrolytes Against Carbon Electrode.

作者信息

Choi Bo-Ra, Park Soo-Jin, Kim Seok

出版信息

J Nanosci Nanotechnol. 2016 Mar;16(3):2765-8. doi: 10.1166/jnn.2016.11062.

DOI:10.1166/jnn.2016.11062
PMID:27455705
Abstract

The ionic performances for the mixture of ethylene carbonate (EC) and dimethylcarbonate (DMC) were investigated for supercapacitor electrolyte. The usage of ethylene carbonate (EC) and dimethylcarbonate (DMC) as organic solvent could solve some problems of acetonitrile (AN). The general aim of present paper is compare to properties of electrochemical properties based on two mixed organic electrolytes. The ionic conductivity, viscosity, and electrochemical performances of EC/DMC+0.1 M TEABF4 mixtures were determined. The ionic conductivity of the electrolytes was measured by AC impedance, and the capacitative performances of the electrolytes were evaluated by using cyclic voltammetry.

摘要

针对超级电容器电解质,研究了碳酸亚乙酯(EC)和碳酸二甲酯(DMC)混合物的离子性能。使用碳酸亚乙酯(EC)和碳酸二甲酯(DMC)作为有机溶剂可以解决乙腈(AN)的一些问题。本文的总体目的是比较基于两种混合有机电解质的电化学性能。测定了EC/DMC + 0.1 M四乙基铵四氟硼酸盐混合物的离子电导率、粘度和电化学性能。通过交流阻抗测量电解质的离子电导率,并使用循环伏安法评估电解质的电容性能。

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