Tatikonda Rajendhraprasad, Bhowmik Sandip, Rissanen Kari, Haukka Matti, Cametti Massimo
University of Jyväskylä, Department of Chemistry, P.O. Box 35, FI-40014 University of Jyväskylä, Finland.
Department of Chemistry, Materials and Chemical Engineering "Giulio Natta" Politecnico di Milano, Via Mancinelli 7, 20131, Milano, Italy.
Dalton Trans. 2016 Aug 9;45(32):12756-62. doi: 10.1039/c6dt02008a.
Terpyridine based ligands 1 and 2, decorated with a C8F17 perfluorinated tag, are able to form stable thermoreversible gels in the presence of several d-block metal chloride salts. The gel systems obtained have been characterized by NMR, X-ray diffraction, electron microscopies and Tgel experiments in order to gain insights into the observed different behaviour of the two similar ligands, also in terms of the effect of additional common anionic species.
基于三联吡啶的配体1和2，带有C8F17全氟标签，在几种d族金属氯化物盐存在的情况下能够形成稳定的热可逆凝胶。为了深入了解观察到的两种相似配体的不同行为，包括额外常见阴离子物种的影响，通过核磁共振、X射线衍射、电子显微镜和凝胶温度实验对所得凝胶体系进行了表征。
