CO2 capture enhancement in InOF-1 via the bottleneck effect of confined ethanol.

作者信息

Peralta Ricardo A, Campos-Reales-Pineda Alberto, Pfeiffer Heriberto, Álvarez J Raziel, Zárate J Antonio, Balmaseda Jorge, González-Zamora Eduardo, Martínez Ana, Martínez-Otero Diego, Jancik Vojtech, Ibarra Ilich A

机构信息

Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Del. Coyoacán, 04510, Ciudad de México, Mexico.

Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, Iztapalapa, C. P. 09340, Ciudad de México, Mexico.

出版信息

Chem Commun (Camb). 2016 Aug 11;52(67):10273-6. doi: 10.1039/c6cc04734c.

DOI:10.1039/c6cc04734c

PMID:27469274

Abstract

CO2 capture of InOF-1 was enhanced 3.6-fold, at 1 bar and 30 °C, by confining EtOH within its pores. Direct visualisation by single crystal X-ray diffraction revealed that EtOH divides InOF-1 channels in wide sections separated by "bottlenecks" caused by EtOH molecules bonded to the μ2-OH functional groups of InOF-1.

摘要