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无设备沉积基于石墨烯的钼氧化物纳米杂化 Langmuir-Blodgett 薄膜用于柔性电致变色面板应用。

Equipment-Free Deposition of Graphene-Based Molybdenum Oxide Nanohybrid Langmuir-Blodgett Films for Flexible Electrochromic Panel Application.

机构信息

School of Molecular Sciences, Arizona State University , Tempe, Arizona 85287-1604, United States.

出版信息

ACS Appl Mater Interfaces. 2016 Aug 24;8(33):21539-44. doi: 10.1021/acsami.6b04985. Epub 2016 Aug 15.

Abstract

The potential electrochromic application of graphene-based nanohybrids is hampered by the challenges in interfacing the electrochromic nanoparticles with graphene at atomic scale and in fabricating their thin film on the substrate through a scalable method. In an effort to overcome these challenges, we demonstrate a highly dispersible graphene-based molybdenum oxide nanohybrid (mRGO-MoO3-x) for flexible electrochromic application. With only a squeeze pipet, mRGO-MoO3-x could be deposited with a high coverage on various substrates through a scalable equipment-free Langmuir-Blodgett film deposition method. By taking advantage of high transmittance benefited from its remarkable thinness, the mRGO-MoO3-x Langmuir-Blodgett film shows a superior reversible electrochromic property with high coloration efficiency on both hard and flexible substrates.

摘要

基于石墨烯的纳米杂化材料在电致变色方面具有很大的应用潜力,但在原子尺度上将电致变色纳米颗粒与石墨烯相连接以及通过可扩展的方法在基底上制备其薄膜方面存在挑战。为了克服这些挑战,我们展示了一种高度可分散的基于石墨烯的氧化钼纳米杂化材料(mRGO-MoO3-x),可用于柔性电致变色应用。仅使用挤压移液管,通过可扩展的无设备 Langmuir-Blodgett 薄膜沉积方法,mRGO-MoO3-x 就可以高覆盖率地沉积在各种基底上。利用其显著的薄膜厚度带来的高透光率,mRGO-MoO3-x 的 Langmuir-Blodgett 薄膜在硬基底和软基底上均表现出优异的可逆电致变色性能和高光色效率。

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