Troadec Thibault, Prades Amparo, Rodriguez Ricardo, Mirgalet Raphael, Baceiredo Antoine, Saffon-Merceron Nathalie, Branchadell Vicenç, Kato Tsuyoshi
Université de Toulouse, UPS, and CNRS , LHFA UMR 5069, F-31062 Toulouse, France.
Université de Toulouse, UPS, and CNRS , ICT FR2599, 118 route de Narbonne, F-31062 Toulouse, France.
Inorg Chem. 2016 Aug 15;55(16):8234-40. doi: 10.1021/acs.inorgchem.6b01505. Epub 2016 Aug 4.
The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic ligand toward transition metals. The strong silylene-metal binding related to both increased σ-donating and π-accepting character of silylene 1 compared to N-heterocyclic carbenes (NHCs) allowed the synthesis of robust and air-stable silylene complexes. Of particular interest, the corresponding platinum(0) complex 6 exhibits high stability and a high level of selectivity and catalytic activity in hydrosilylation reactions that is superior to that of the related NHC-Pt(0) complexes.
碱稳定的硅环丙叉 1 作为一种对过渡金属具有多种用途的强亲核配体。与 N - 杂环卡宾（NHCs）相比，硅烯 1 的 σ 供电子和 π 吸电子特性增强，这使得其与金属形成的强硅烯 - 金属键得以实现，从而能够合成出稳定且对空气稳定的硅烯配合物。特别值得关注的是，相应的铂（0）配合物 6 在硅氢化反应中表现出高稳定性、高选择性和催化活性，优于相关的 NHC - Pt（0）配合物。
