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6-甲基-8-十六碳烯酸:一种来自海洋海绵锚状Desmapsama的新型脂肪酸。

6-methyl-8-hexadecenoic acid: A novel fatty acid from the marine spongeDesmapsama anchorata.

作者信息

Carballeira N M, Maldonado M E

机构信息

Department of Chemistry, University of Puerto Rico, 00931, Rio Piedras, Puerto Rico.

出版信息

Lipids. 1988 Jul;23(7):690-3. doi: 10.1007/BF02535670.

Abstract

The novel fatty acid 7-methyl-8-hexadecenoic (1) was identified in the marine spongeDesmapsama anchorata. Other interesting fatty acids identified were 14-methyl-8-hexadecenoic (2), better known through its methyl ester as one of the components of the sex attractant of the female dermestid beetle, and the saturated fatty acid 3-methylheptadecanoic (3), known to possess larvicidal activity. The main phospholipid fatty acids encountered inD. anchorata were palmitic (16∶0), behenic (22∶0) and 5,9-hexacosadienoic acid (26∶2), which together accounted for 50% of the total phospholipid fatty acid mixture.

摘要

在海洋海绵Desmapsama anchorata中鉴定出了新型脂肪酸7-甲基-8-十六碳烯酸(1)。鉴定出的其他有趣脂肪酸包括14-甲基-8-十六碳烯酸(2),其甲酯作为雌性皮蠹甲虫性引诱剂的成分之一更为人所知,以及饱和脂肪酸3-甲基十七烷酸(3),已知其具有杀幼虫活性。在Desmapsama anchorata中遇到的主要磷脂脂肪酸为棕榈酸(16∶0)、山嵛酸(22∶0)和5,9-二十六碳二烯酸(26∶2),它们共同占磷脂脂肪酸混合物总量的50%。

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