Langley Stuart K, Wielechowski Daniel P, Moubaraki Boujemaa, Murray Keith S
School of Science and the Environment, Chemistry Division, Manchester Metropolitan University, Manchester, UK.
Chem Commun (Camb). 2016 Sep 21;52(73):10976-9. doi: 10.1039/c6cc06152d. Epub 2016 Aug 17.
Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrLn} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.
在一系列{CrLn}(Ln = Tb、Dy和Ho)单分子磁体中,用2-氯-4,5-氟苯甲酸酯取代桥连苯甲酸酯配体,可显著提高磁弛豫时间、磁滞阻塞温度和矫顽力。