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薄向列润湿膜中的胶体粒子。

Colloidal Particles in Thin Nematic Wetting Films.

机构信息

Université de Tunis El Manar , Faculté des Sciences de Tunis, LR99ES16 Laboratoire Physique de la Matière Molle et de la Modélisation Electromagnétique, 2092, Tunis, Tunisia.

Max-Planck-Institut für Intelligente Systeme , Heisenbergstraße 3, D-70569 Stuttgart, Germany.

出版信息

Langmuir. 2016 Sep 6;32(35):9097-107. doi: 10.1021/acs.langmuir.6b02701. Epub 2016 Aug 26.

Abstract

We experimentally and theoretically study the variety of elastic deformations that appear when colloidal inclusions are embedded in thin wetting films of a nematic liquid crystal with hybrid anchoring conditions. In the thickest films, the elastic dipoles formed by particles and their accompanying defects share features with the patterns commonly observed in liquid crystal cells. When the film gets thinner than the particles size, however, the capillary effects strongly modify the appearance of the elastic dipoles and the birefringence patterns. The influence of the film thickness and particles sizes on the patterns has been explored. The main experimental features and the transitions observed at large scale-with respect to the inclusions' size-are explained with a simple two-dimensional Ansatz, combining capillarity and nematic elasticity. In a second step, we discuss the origin of the variety of observed textures. Developing a three-dimensional Landau-de Gennes model at the scale of the particles, we show that the presence of free interfaces and the beads confinement yield metastable configurations that are quenched during the film spreading or the beads trapping at interfaces.

摘要

我们通过实验和理论研究了在具有混合锚定条件的向列液晶的薄湿膜中嵌入胶体粒子时出现的各种弹性变形。在最厚的膜中,由粒子形成的弹性偶极子及其伴随的缺陷与在液晶盒中通常观察到的图案具有共同的特征。然而,当膜厚度小于粒子尺寸时,毛细作用会强烈改变弹性偶极子和双折射图案的外观。我们研究了膜厚度和粒子尺寸对图案的影响。主要的实验特征和在大范围内观察到的转变(相对于粒子的大小),用一个简单的二维假设来解释,该假设结合了毛细作用和向列弹性。在第二步中,我们讨论了观察到的各种纹理的起源。在粒子尺度上发展一个三维的 Landau-de Gennes 模型,我们表明自由界面的存在和珠粒的限制导致了在膜扩展或珠粒在界面处捕获时被猝灭的亚稳态构型。

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