Jeridi Haifa, Gharbi Mohamed A, Othman Tahar, Blanc Christophe
Université de Tunis El Manar, Faculté des Sciences de Tunis, LR99ES16 Laboratoire Physique de la Matière Molle et de la Modélisation Électromagnétique, 2092, Tunis, Tunisia;
Department of Physics, McGill University, Montreal, QC H3A 2T8, Canada;
Proc Natl Acad Sci U S A. 2015 Dec 1;112(48):14771-6. doi: 10.1073/pnas.1508865112. Epub 2015 Nov 9.
Directed and true self-assembly mechanisms in nematic liquid crystal colloids rely on specific interactions between microparticles and the topological defects of the matrix. Most ordered structures formed in thin nematic cells are thus based on elastic multipoles consisting of a particle and nearby defects. Here, we report, for the first time to our knowledge, the existence of giant elastic dipoles arising from particles dispersed in free nematic liquid crystal films. We discuss the role of capillarity and film thickness on the dimensions of the dipoles and explain their main features with a simple 2D model. Coupling of capillarity with nematic elasticity could offer ways to tune finely the spatial organization of complex colloidal systems.
向列型液晶胶体中的定向和真实自组装机制依赖于微粒与基质拓扑缺陷之间的特定相互作用。因此,在向列型薄液晶盒中形成的大多数有序结构都是基于由一个粒子和附近缺陷组成的弹性多极子。据我们所知,在此我们首次报道了在自由向列型液晶薄膜中分散的粒子产生的巨大弹性偶极子的存在。我们讨论了毛细作用和薄膜厚度对偶极子尺寸的作用,并用一个简单的二维模型解释了它们的主要特征。毛细作用与向列型弹性的耦合可以提供微调复杂胶体系统空间组织的方法。