超灵敏光致变色碘铜酸盐（I）杂化物
Ultrasensitive Photochromic Iodocuprate(I) Hybrid.
作者信息
Shen Jun-Ju, Li Xiang-Xia, Yu Tan-Lai, Wang Feng, Hao Peng-Fei, Fu Yun-Long
机构信息
School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, China.
出版信息
Inorg Chem. 2016 Sep 6;55(17):8271-3. doi: 10.1021/acs.inorgchem.6b01599. Epub 2016 Aug 19.
By employing in situ methylnicotinohydrazide dication (MNH(2+)) as an electron acceptor, we have constructed an iodocuprate(I) hybrid {[MNH][Cu2I3]2}n (1), which exhibits charge transfer (CT) thermochromism due to the intense absorption of CT and electron transfer (ET) photochromism with high photocoloration contrast and fast response to UV irradiation due to the synergetic effect of valence change of copper ions.
通过使用原位甲基烟酰肼二价阳离子（MNH(2+)）作为电子受体，我们构建了一种碘铜酸盐（I）杂化物{[MNH][Cu2I3]2}n（1），由于电荷转移（CT）的强烈吸收，它表现出电荷转移（CT）热致变色，并且由于铜离子价态变化的协同效应，具有电子转移（ET）光致变色，具有高光色对比度和对紫外线照射的快速响应。
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