Li Guoping, Hao Pengfei, Shen Junju, Yu Tanlai, Li Huihui, Fu Yunlong
School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, P. R. China.
Inorg Chem. 2016 Nov 7;55(21):11342-11347. doi: 10.1021/acs.inorgchem.6b01906. Epub 2016 Oct 21.
Matched with 3,5-bis(pyridine-2-yl)-1,2,4-triazole (2-bpt), a new electron donor-acceptor-based chlorobismuthate(III) hybrid, [2-bpt][BiCl(HO)]·5HO was prepared solvothermally and characterized. The title compound (hydrated form) and its dehydrated form exhibit photo- and thermo-induced intermolecular electron transfer (ET), which correspond to dual ET photo/thermochromism for hydrated form, charge transfer thermochromism during dehydration, and simultaneously photoluminescent responses, respectively.
与3,5-双（吡啶-2-基）-1,2,4-三唑（2-bpt）相匹配，通过溶剂热法制备并表征了一种基于新型电子供体-受体的氯铋酸盐（III）杂化物[2-bpt][BiCl(HO)]·5HO。标题化合物（水合形式）及其脱水形式表现出光致和热致分子间电子转移（ET），分别对应于水合形式的双ET光/热致变色、脱水过程中的电荷转移热致变色以及同时的光致发光响应。
