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用于优化热电功率的纳米线中的阶梯式量子点结构

Staircase Quantum Dots Configuration in Nanowires for Optimized Thermoelectric Power.

作者信息

Li Lijie, Jiang Jian-Hua

机构信息

Multidisciplinary Nanotechnology Centre, College of Engineering, Swansea University, Bay Campus, Swansea, SA1 8QQ, UK.

College of Physics, Optoelectronics and Energy, &Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006, China.

出版信息

Sci Rep. 2016 Aug 23;6:31974. doi: 10.1038/srep31974.

Abstract

The performance of thermoelectric energy harvesters can be improved by nanostructures that exploit inelastic transport processes. One prototype is the three-terminal hopping thermoelectric device where electron hopping between quantum-dots are driven by hot phonons. Such three-terminal hopping thermoelectric devices have potential in achieving high efficiency or power via inelastic transport and without relying on heavy-elements or toxic compounds. We show in this work how output power of the device can be optimized via tuning the number and energy configuration of the quantum-dots embedded in parallel nanowires. We find that the staircase energy configuration with constant energy-step can improve the power factor over a serial connection of a single pair of quantum-dots. Moreover, for a fixed energy-step, there is an optimal length for the nanowire. Similarly for a fixed number of quantum-dots there is an optimal energy-step for the output power. Our results are important for future developments of high-performance nanostructured thermoelectric devices.

摘要

利用非弹性输运过程的纳米结构可以提高热电能量采集器的性能。一种原型是三端跳跃热电器件,其中量子点之间的电子跳跃由热声子驱动。这种三端跳跃热电器件具有通过非弹性输运实现高效率或高功率的潜力,且不依赖重金属元素或有毒化合物。在这项工作中,我们展示了如何通过调整嵌入平行纳米线中的量子点的数量和能量配置来优化器件的输出功率。我们发现,具有恒定能量步长的阶梯状能量配置比单对量子点的串联连接能提高功率因数。此外,对于固定的能量步长,纳米线存在一个最佳长度。类似地,对于固定数量的量子点,输出功率存在一个最佳能量步长。我们的结果对于高性能纳米结构热电器件的未来发展具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c86e/4994073/079cda2d82ef/srep31974-f1.jpg

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