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源自具有增强的甲酸氧化活性的钯镍核壳纳米颗粒的三元钯镍磷混合电催化剂。

Ternary Pd-Ni-P hybrid electrocatalysts derived from Pd-Ni core-shell nanoparticles with enhanced formic acid oxidation activity.

作者信息

Liang Xin, Liu Bo, Zhang Juntao, Lu Siqi, Zhuang Zhongbin

机构信息

State Key Lab of Organic-Inorganic Composites and College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China.

出版信息

Chem Commun (Camb). 2016 Sep 25;52(74):11143-6. doi: 10.1039/c6cc04382h. Epub 2016 Aug 23.

DOI:10.1039/c6cc04382h
PMID:27550830
Abstract

Ternary Pd-Ni-P hybrid electrocatalysts were synthesized through low temperature phosphidation of Pd-Ni core-shell nanoparticles. They show enhanced formic acid electro-oxidation activity compared to Pd, Pd-Ni and Pd-P nanoparticles, which is ascribed to the synergistic effect of the Ni and P components with Pd.

摘要

通过对钯镍核壳纳米颗粒进行低温磷化反应,合成了三元钯 - 镍 - 磷混合电催化剂。与钯、钯镍和钯磷纳米颗粒相比,它们表现出增强的甲酸电氧化活性,这归因于镍和磷组分与钯的协同效应。

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