Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai, 40019, India.
Chemical Engineering Department, Gharda Institute of Technology, Lavel, Tal. Khed, 415708, India.
Top Curr Chem (Cham). 2016 Oct;374(5):61. doi: 10.1007/s41061-016-0064-9. Epub 2016 Aug 20.
Sonochemical reactors are based on the generation of cavitational events using ultrasound and offer immense potential for the intensification of physical and chemical processing applications. The present work presents a critical analysis of the underlying mechanisms for intensification, available reactor configurations and overview of the different applications exploited successfully, though mostly at laboratory scales. Guidelines have also been presented for optimum selection of the important operating parameters (frequency and intensity of irradiation, temperature and liquid physicochemical properties) as well as the geometric parameters (type of reactor configuration and the number/position of the transducers) so as to maximize the process intensification benefits. The key areas for future work so as to transform the successful technique at laboratory/pilot scale into commercial technology have also been discussed. Overall, it has been established that there is immense potential for sonochemical reactors for process intensification leading to greener processing and economic benefits. Combined efforts from a wide range of disciplines such as material science, physics, chemistry and chemical engineers are required to harness the benefits at commercial scale operation.
声化学反应器基于超声空化现象的产生,并为物理和化学加工应用的强化提供了巨大的潜力。本工作对强化的基本机制、可用的反应器结构以及成功应用的不同领域进行了批判性分析,尽管这些应用大多处于实验室规模。还提出了一些准则,以优化重要操作参数(辐照频率和强度、温度和液体物理化学性质)以及几何参数(反应器结构类型和换能器的数量/位置)的选择,以最大限度地提高过程强化的效益。还讨论了将实验室/中试规模的成功技术转化为商业技术的未来工作的重点领域。总的来说,声化学反应器在强化过程方面具有巨大的潜力,可以实现更绿色的加工和经济效益。需要来自材料科学、物理、化学和化学工程等多个学科的广泛合作,才能在商业规模操作中利用这些好处。