Preinfalk Alexander, Misale Antonio, Maulide Nuno
Faculty of Chemistry, Institute of Organic Chemistry, University of Vienna, Währinger Strasse 38, 1090, Vienna, Austria.
Chemistry. 2016 Oct 4;22(41):14471-4. doi: 10.1002/chem.201603154. Epub 2016 Sep 6.
The reaction of aryl-substituted allenes with alcohols under gold catalysis led to highly substituted indenes in good yields, with low catalyst loading and under mild conditions. During this domino transformation, two C-C bonds are formed with water as the only byproduct.
在金催化下，芳基取代的丙二烯与醇反应，能以良好的产率、低催化剂用量且在温和条件下生成高度取代的茚。在这一多米诺转化过程中，形成了两个碳 - 碳键，且仅产生水作为副产物。
