Prasanna Kumar J B, Ramgopal G, Sunitha D V, Prasad B Daruka, Nagabhushana H, Vidya Y S, Anantharaju K S, Prashantha S C, Sharma S C, Prabhakara K R
Department of Physics, GFGC Tumkur, Tumkur, 572 102, Karnataka, India.
Department of Physics, Sathyabama University, Chennai, 600 119, Tamilnadu, India.
Luminescence. 2017 May;32(3):414-424. doi: 10.1002/bio.3197. Epub 2016 Sep 12.
Cr -doped Y O (0.5-9 mol%) was synthesized by a simple solution combustion method using Aloe vera gel as a fuel/surfactant. The final obtained product was calcined at 750°C for 3 h, which is the lowest temperature reported so far for the synthesis of this compound. The calcined product was confirmed for its crystallinity and purity by powder X-ray diffraction (PXRD) studies which showed a single-phase nano cubic phosphor. The particles size estimated by Scherrer formula was in the range of 6-19 nm. The UV-vis spectra showed absorption bands at 198, 272 and 372 nm having band gap energy in the range 4.00-4.26 eV. In order to investigate the possibility of its use in white light emitting display applications, the photoluminescence properties of Cr -doped Y O nanophosphors were studied at an excitation wavelength in the near ultraviolet (UV) light region (361 nm). The emission spectra consisted of emission peaks in the blue ( F → H ), orange ( F → H ) and red ( F → H ) regions. The CIE coordinates (0.33, 0.33) lie in the white light region. Hence Y O :Cr can be used for white light-emitting diode (LED) applications.
采用简单的溶液燃烧法,以芦荟凝胶作为燃料/表面活性剂,合成了Cr掺杂的Y₂O₃(0.5 - 9 mol%)。最终得到的产物在750°C下煅烧3小时,这是迄今为止报道的合成该化合物的最低温度。通过粉末X射线衍射(PXRD)研究确认了煅烧产物的结晶度和纯度,结果显示为单相纳米立方磷光体。用谢乐公式估算的颗粒尺寸在6 - 19纳米范围内。紫外可见光谱显示在198、272和372纳米处有吸收带,带隙能量在4.00 - 4.26电子伏特范围内。为了研究其在白光发光显示应用中的可能性,在近紫外(UV)光区域(361纳米)的激发波长下研究了Cr掺杂的Y₂O₃纳米磷光体的光致发光特性。发射光谱由蓝色(F→H)、橙色(F→H)和红色(F→H)区域的发射峰组成。CIE坐标(0.33,0.33)位于白光区域。因此,Y₂O₃:Cr可用于白光发光二极管(LED)应用。