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使用硫代甘油作为燃料的燃烧法低温合成 Y<sub>2</sub>O<sub>3</sub>:Eu<sup>3+</sup>纳米荧光粉及其在近紫外光发射二极管中的应用。

Novel low-temperature synthesis of Y O :Eu nanophosphor using combustion with thioglycerol as fuel for near-UV light-emitting diodes.

机构信息

Bharati Vidyapeeth's College of Engineering for Women, Pune, India.

R.S. Bidkar College, Hinganghat, India.

出版信息

Luminescence. 2023 Nov;38(11):1921-1928. doi: 10.1002/bio.4580. Epub 2023 Sep 15.

Abstract

Luminescent materials used in flat panel displays, compact fluorescent lamps, and light-emitting diodes require high purity, uniform particle size, clean surfaces, spherical shape, and dense morphology to ensure long-term stability. Y O :Eu is a widely studied red phosphor known for its characteristic photoluminescence (PL) emission at 613 nm with near-UV excitation at 392 nm. Many methods have been explored to synthesize Y O :Eu nanoparticles with exceptional purity, consistent phases, and uniform particle sizes. The aim is to synthesize particles with pristine surfaces, spherical shape, and compact morphology. This study focuses on the low-temperature synthesis and PL investigation of Y O :Eu nanophosphors using combustion with thioglycerol as fuel. The results are compared with Y O :Eu red nanophosphors synthesized using wet chemical and nitrate combustion methods. The PL characteristics of the Y O :Eu nanophosphors were analyzed using PL emission spectroscopy, X-ray diffraction, and scanning electron microscopy. These findings highlight the advantageous properties of the synthesized nanophosphors, such as their suitability for solid-state lighting applications in the lamp industry as highly efficient red phosphors. The combination of high purity, uniform particle size, clean surfaces, spherical shape, and dense morphology contributes to their potential for long-term stability and reliable performance in lighting devices.

摘要

用于平板显示器、紧凑型荧光灯和发光二极管的发光材料需要高纯度、均匀的粒径、清洁的表面、球形和致密的形态,以确保长期稳定性。Y2O3:Eu 是一种广泛研究的红色荧光粉,其特征在于在近紫外光 392nm 激发下发出 613nm 的光致发光(PL)发射。已经探索了许多方法来合成具有异常纯度、一致相和均匀粒径的 Y2O3:Eu 纳米粒子。目的是合成具有原始表面、球形和致密形态的颗粒。本研究专注于使用硫代甘油作为燃料的燃烧法低温合成和 PL 研究 Y2O3:Eu 纳米荧光粉。结果与使用湿化学和硝酸盐燃烧法合成的 Y2O3:Eu 红色纳米荧光粉进行了比较。使用 PL 发射光谱、X 射线衍射和扫描电子显微镜分析了 Y2O3:Eu 纳米荧光粉的 PL 特性。这些发现强调了合成纳米荧光粉的有利特性,例如它们适合作为高效红色荧光粉在灯工业中的固态照明应用。高纯度、均匀的粒径、清洁的表面、球形和致密的形态的结合有助于它们在照明设备中具有长期稳定性和可靠性能的潜力。

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