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用碱性电解水去除豇豆中的六种农药残留

Removal of six pesticide residues in cowpea with alkaline electrolysed water.

作者信息

Han Yongtao, Song Le, An Quanshun, Pan Canping

机构信息

Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, 100193, P.R. China.

出版信息

J Sci Food Agric. 2017 Jun;97(8):2333-2338. doi: 10.1002/jsfa.8043. Epub 2016 Oct 25.

Abstract

BACKGROUND

Reduction of six pesticide residues (isoprocarb, chlorpyrifos, bifenthrin, beta-cypermethrin, difenoconazole and azoxystrobin) in cowpea by alkaline electrolysed water (AlEW) solutions with different pH was investigated. The commonly used washing treatments in household processing were used for comparison.

RESULTS

The residue magnitudes were determined by gas chromatography coupled with tandem mass spectrometry (GC-MS/MS). Results showed that the removal effect of AlEW solution on the six pesticides was superior to tap water, 5% sodium chloride, 5% sodium carbonate and 5% acetic acid solution. AlEW with pH 12.2 had more potential to eliminate the six pesticides in cowpeas. Moreover, the reduction of pesticide residues gradually increased with the increase of washing time.

CONCLUSION

This study demonstrated that AlEW solution with pH of 12.2 could be used to reduce pesticide residues on fresh cowpea samples. © 2016 Society of Chemical Industry.

摘要

背景

研究了不同pH值的碱性电解水(AlEW)溶液对豇豆中六种农药残留(异丙威、毒死蜱、联苯菊酯、高效氯氰菊酯、苯醚甲环唑和嘧菌酯)的去除效果。并与家庭加工中常用的洗涤处理方法进行了比较。

结果

采用气相色谱-串联质谱法(GC-MS/MS)测定残留量。结果表明,AlEW溶液对六种农药的去除效果优于自来水、5%氯化钠、5%碳酸钠和5%乙酸溶液。pH值为12.2的AlEW对豇豆中六种农药的去除潜力更大。此外,农药残留量的降低随着洗涤时间的增加而逐渐增加。

结论

本研究表明,pH值为12.2的AlEW溶液可用于降低新鲜豇豆样品上的农药残留。©2016化学工业协会。

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