State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P.R. China.
Institute of Theoretical Chemistry, Jilin University, Changchun, 130023, P.R. China.
Chemistry. 2016 Nov 2;22(45):16230-16235. doi: 10.1002/chem.201603102. Epub 2016 Sep 20.
Two new isostructural 3D lanthanide-organic frameworks [H N(Me) ] [Ln (OH)(bpt) (H O) ] (DMF) ⋅(H O) (1-Ln; Ln=Sm and Eu) with a 1D channel (25 Å) have been successfully assembled from the rare trinuclear [Ln (OH)(COO) ] clusters and biphenyl-3,4',5-tricarboxylic acid (H bpt) and exhibit high stability towards water in the pH range 3-10. MOF 1-Eu is a promising luminescent probe for sensing Fe in aqueous solution and is also selective towards rhodamine B (RhB) with a superior adsorption capacity of 735 mg g , which is the highest among the reported Ln-MOFs for RhB removal so far. Periodic DFT calculations further confirmed the selective adsorption of rhodamine B over other dyes.
两个新的同构 3D 镧系有机骨架[H N(Me) ] [Ln (OH)(bpt) (H O) ] (DMF) ⋅(H O) (1-Ln; Ln=Sm 和 Eu) 由罕见的三核[Ln (OH)(COO) ] 簇和联苯-3,4',5-三甲酸 (H bpt) 成功组装而成，具有 1D 通道（25 Å），在 pH 值为 3-10 的范围内对水具有高稳定性。MOF 1-Eu 是一种很有前途的用于感测水溶液中 Fe 的发光探针，对罗丹明 B (RhB) 也具有选择性，吸附容量高达 735 mg g ，是迄今为止报道的用于去除 RhB 的 Ln-MOFs 中最高的。周期性 DFT 计算进一步证实了罗丹明 B 对其他染料的选择性吸附。
