Longhi Giovanna, Castiglioni Ettore, Koshoubu Jun, Mazzeo Giuseppe, Abbate Sergio
Department of Molecular and Translational Medicine, Università di Brescia, Brescia, Italy.
JASCO Europe, Cremella (LC), Italy.
Chirality. 2016 Oct;28(10):696-707. doi: 10.1002/chir.22647.
We review the present status of experiments and calculations for circularly polarized luminescence (CPL) of simple organic molecules and of stimuli-responsive organic molecules. Together with the historical report of the main instrumental approaches, a few crucial points about experiments are tackled, with the aim of defining measurement protocols, in view of the wide availability of commercial apparatuses in the near future. The calculations aimed at interpreting the CPL spectra, mostly based on time-dependent Density Functional Theory (TD-DFT) calculations, which started around 2010, are reviewed, limiting the discussion to small to mid-sized molecules. Some applications of CPL spectra of organic molecules-based systems are presented, with a focus especially on two fields: material science and biology. Chirality 28:696-707, 2016. © 2016 Wiley Periodicals, Inc.
我们综述了简单有机分子和刺激响应性有机分子圆偏振发光（CPL）的实验和计算现状。结合主要仪器方法的历史报告，探讨了一些关于实验的关键点，目的是鉴于在不久的将来商业仪器的广泛可得性来定义测量方案。对旨在解释CPL光谱的计算进行了综述，这些计算主要基于大约2010年开始的含时密度泛函理论（TD-DFT）计算，讨论限于中小尺寸分子。介绍了基于有机分子体系的CPL光谱的一些应用，尤其着重于两个领域：材料科学和生物学。《手性》28:696 - 707，2016年。© 2016威利期刊公司。
