源自手性五齿配体asN4Py的非血红素氧代铁（IV）配合物的形成、表征及反应活性
Formation, Characterization, and Reactivity of a Nonheme Oxoiron(IV) Complex Derived from the Chiral Pentadentate Ligand asN4Py.
作者信息
Lakk-Bogáth Dóra, Csonka Róbert, Speier Gábor, Réglier Marius, Simaan A Jalila, Naubron Jean-Valère, Giorgi Michel, Lázár Károly, Kaizer József
机构信息
Department of Chemistry, University of Pannonia , 8201 Veszprém, Hungary.
Aix Marseille Université, CNRS, Centrale Marseille, iSm2 UMR 7313 , 13397 Marseille, France.
出版信息
Inorg Chem. 2016 Oct 17;55(20):10090-10093. doi: 10.1021/acs.inorgchem.6b01089. Epub 2016 Sep 26.
The chiral pentadentate low-spin (S = 1) oxoiron(IV) complex [Fe(O)(asN4Py)] (2) was synthesized and spectroscopically characterized. Its formation kinetics, reactivity, and (enantio)selectivity in an oxygen-atom-transfer reaction was investigated in detail and compared to a similar pentadentate ligand-containing system.
手性五齿低自旋（S = 1）氧代铁（IV）配合物[Fe(O)(asN4Py)]（2）被合成并通过光谱进行了表征。详细研究了其在氧原子转移反应中的形成动力学、反应性和（对映体）选择性，并与类似的含五齿配体体系进行了比较。
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