Jiang Ying, Li Shiben, Chen Jeff Z Y
School of Chemistry and Environment, Center of Soft Matter Physics and its Applications, Beihang University, 100191, Beijing, China.
Department of Physics, Wenzhou University, 325035, Wenzhou, Zhejiang, China.
Eur Phys J E Soft Matter. 2016 Oct;39(10):91. doi: 10.1140/epje/i2016-16091-8. Epub 2016 Oct 4.
We review a formalism that can be used to calculate the microphase-separated crystallographic structures of multi-component wormlike polymer melts. The approach is based on a self-consistent field theory of wormlike polymers where the persistence length of each component is an important parameter. We emphasize on an analysis of the number of independent parameters required to specify a problem in general, for a system that includes Flory-Huggins and Maier-Saupe energies. Examples of recent applications are also briefly demonstrated: AB homopolymer interface, AB diblock copolymers, and rod-coil copolymers.
我们回顾了一种可用于计算多组分蠕虫状聚合物熔体微相分离晶体结构的形式体系。该方法基于蠕虫状聚合物的自洽场理论，其中各组分的持久长度是一个重要参数。我们着重分析了一般情况下指定一个问题所需的独立参数数量，该问题涉及一个包含弗洛里 - 哈金斯（Flory-Huggins）和迈尔 - 绍佩（Maier-Saupe）能量的体系。还简要展示了近期应用的实例：AB均聚物界面、AB二嵌段共聚物和棒 - 线圈共聚物。
