Evlashin Stanislav, Dyakonov Pavel, Khmelnitsky Roman, Dagesyan Sarkis, Klokov Andrey, Sharkov Andrey, Timashev Peter, Minaeva Svetlana, Maslakov Konstantin, Svyakhovskiy Sergey, Suetin Nikolay
P. N. Lebedev Physical Institute, Russian Academy of Sciences , 53 Leninsky Prospect, 119991 Moscow, Russia.
Institute on Laser and Information Technologies RAS , 2 Pionerskaya,142092 Troitsk, Russia.
ACS Appl Mater Interfaces. 2016 Oct 26;8(42):28880-28887. doi: 10.1021/acsami.6b10145. Epub 2016 Oct 12.
This article presents a new simple method of creating light-absorbing carbon material for optical devices such as bolometers. A simple method of laser microstructuring of graphene oxide is used in order to create such material. The absorption values of more than 98% in the visible and more than 90% in the infrared range are achieved. Moreover thermal properties of the films, such as temperature dependence and the thermal response of the samples, are studied. The change in resistance with temperature is 13 Ohm K, temperature coefficient of resistance (TCR) is 0.3% K, and the sensitivity is 0.17 V W at 300 K. Thermal conductivity is rather high at ∼104 W m K at 300 K. The designed bolometer operates at room temperature using incandescent lamp as a light source. This technique suggests a new inexpensive way to create a selective absorption coating and/or active layer for optical devices. Developed GO and rGO films have a large surface area and high conductivity. These properties make carbon coatings a perfect candidate for creating a new type of optoelectronic devices (gas sensors, detectors of biological objects, etc.).
本文介绍了一种为测辐射热计等光学器件制造吸光碳材料的新的简单方法。为制造这种材料,采用了一种氧化石墨烯激光微结构化的简单方法。在可见光范围内实现了超过98%的吸收率,在红外范围内实现了超过90%的吸收率。此外,还研究了薄膜的热性能,如温度依赖性和样品的热响应。电阻随温度的变化为13欧姆每开尔文,电阻温度系数(TCR)为0.3%每开尔文,在300K时灵敏度为0.17伏每瓦。在300K时热导率相当高,约为104瓦每米每开尔文。所设计的测辐射热计在室温下以白炽灯作为光源工作。该技术为光学器件制造选择性吸收涂层和/或有源层提供了一种新的廉价方法。所开发的氧化石墨烯和还原氧化石墨烯薄膜具有大表面积和高导电性。这些特性使碳涂层成为制造新型光电器件(气体传感器、生物物体探测器等)的理想候选材料。