由高度分支的正交堆叠纳米片组成的分级硅沸石-1八面体作为气相贝克曼重排的高效催化剂。
Hierarchical silicalite-1 octahedra comprising highly-branched orthogonally-stacked nanoplates as efficient catalysts for vapor-phase Beckmann rearrangement.
作者信息
Chang Albert, Hsiao Hsu-Ming, Chen Tsai-Hsiu, Chu Ming-Wen, Yang Chia-Min
机构信息
Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan.
Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan.
出版信息
Chem Commun (Camb). 2016 Sep 29;52(80):11939-11942. doi: 10.1039/c6cc05992a.
PMID:27711276
Abstract
A triblock structure-directing agent was designed to synthesize hierarchical silicalite-1 octahedra comprising highly-branched, orthogonally-stacked and self-pillared nanoplates that exhibited excellent and stable activity for the vapor-phase Beckmann rearrangement of cyclic oximes and high lactam selectivity.
摘要
设计了一种三嵌段结构导向剂，用于合成具有高度分支、正交堆叠和自支撑纳米片的分级硅沸石-1八面体，该八面体对环状肟的气相贝克曼重排表现出优异且稳定的活性以及高内酰胺选择性。
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