对苯二酚被一种（水杨醛缩邻氨基酚）钌（Ⅵ）氮配合物氧化。
Oxidation of hydroquinones by a (salen)ruthenium(vi) nitrido complex.
作者信息
Xie Jianhui, Lo Po-Kam, Lam William W Y, Man Wai-Lun, Ma Li, Yiu Shek-Man, Lau Kai-Chung, Lau Tai-Chu
机构信息
Department of Biology and Chemistry and Institute of Molecular Functional Materials, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong, China.
出版信息
Chem Commun (Camb). 2016 Sep 15;52(76):11430-11433. doi: 10.1039/c6cc06231h.
Hydroquinone is readily oxidized by a (salen)ruthenium(vi) nitrido complex in the presence of pyridine to give benzoquinone. Experimental and computational studies suggest that the reaction occurs via a novel mechanism that involves an initial electrophilic attack at the aromatic ring of the hydroquinone by the nitrido ligand.
在吡啶存在下，对苯二酚很容易被（水杨醛缩邻苯二胺）钌（Ⅵ）氮化物配合物氧化生成苯醌。实验和计算研究表明，该反应通过一种新机制发生，该机制涉及氮化物配体对苯二酚芳环的初始亲电攻击。
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