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金属有机框架衍生的石墨烯@氮掺杂碳@超细TiO纳米复合材料作为钠离子电池的高倍率长寿命阳极

Metal-organic framework-derived graphene@nitrogen doped carbon@ultrafine TiO nanocomposites as high rate and long-life anodes for sodium ion batteries.

作者信息

Zhang Zhen, An Yongling, Xu Xiaoyan, Dong Chenglong, Feng Jinkui, Ci Lijie, Xiong Shenglin

机构信息

Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan 250061, China.

School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China.

出版信息

Chem Commun (Camb). 2016 Oct 25;52(87):12810-12812. doi: 10.1039/c6cc07346h.

DOI:10.1039/c6cc07346h
PMID:27747337
Abstract

Graphene@nitrogen doped carbon@ultrafine TiO nanoparticles (G-NC@TiO) with porous structure are obtained through annealing the precursor of graphene oxide/metal-organic frameworks (MOFs) for the first time. As an anode material for sodium ion batteries (SIB), the G-NC@TiO composite can deliver an excellent capacity retention of 93% even after 5000 cycles, and a superior rate capability.

摘要

通过首次对氧化石墨烯/金属有机框架(MOF)前驱体进行退火处理,获得了具有多孔结构的石墨烯@氮掺杂碳@超细TiO纳米颗粒(G-NC@TiO)。作为钠离子电池(SIB)的负极材料,G-NC@TiO复合材料即使在5000次循环后仍能保持93%的优异容量保持率,以及卓越的倍率性能。

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