Liu Jing, Fu Xiangyu, Chen Qiwei, Zhang Yajie, Wang Yongfeng, Zhao Dahui, Chen Wei, Xu Guo Qin, Liao Peilin, Wu Kai
BNLMS, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
MOE Key Lab of Polymer Chemistry & Physics, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Chem Commun (Camb). 2016 Oct 27;52(88):12944-12947. doi: 10.1039/c6cc06444b.
Ordered two-dimensional arrays of silver adatoms with tunable metal atom density stabilized by 1,4-diethynyl-2,5-dimethylbenzene, a terminal alkyne, were prepared on Ag(111) and scrutinized by scanning tunneling microscopy and density functional theory calculations. Stabilization of the adatom arrays was attributed to the substrate-mediated electron localizations of the Ag adatom and terminal alkynyl in the molecule.
通过终端炔烃1,4 - 二乙炔基 - 2,5 - 二甲基苯在Ag(111)上制备了具有可调金属原子密度的有序二维银吸附原子阵列，并通过扫描隧道显微镜和密度泛函理论计算进行了仔细研究。吸附原子阵列的稳定性归因于分子中Ag吸附原子和终端炔基的底物介导电子定位。
