Hoshimoto Yoichi, Hayashi Yukari, Ohashi Masato, Ogoshi Sensuke
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan.
Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan.
Chem Asian J. 2017 Feb 1;12(3):278-282. doi: 10.1002/asia.201601313. Epub 2017 Jan 3.
A combined kinetic and theoretical study was conducted in order to clarify the details on the reaction mechanism for Ni /ItBu-catalyzed intramolecular alkene hydroacylation. The results confirm the hypothesis that this intramolecular hydroacylation proceeds through an oxanickelacycle key intermediate.
为了阐明镍/三叔丁基膦催化分子内烯烃氢酰化反应机理的细节，进行了动力学和理论相结合的研究。结果证实了该分子内氢酰化反应通过氧杂镍环关键中间体进行的假设。
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