White Helen K, Wang Chloe H, Williams Patrick L, Findley David M, Thurston Alana M, Simister Rachel L, Aeppli Christoph, Nelson Robert K, Reddy Christopher M
Department of Chemistry, Haverford College, 370 Lancaster Avenue, Haverford, PA 19041, USA.
Department of Chemistry, Haverford College, 370 Lancaster Avenue, Haverford, PA 19041, USA.
Mar Pollut Bull. 2016 Dec 15;113(1-2):380-386. doi: 10.1016/j.marpolbul.2016.10.029. Epub 2016 Oct 15.
To investigate the long-term weathering of oil from the Deepwater Horizon (DWH) incident, oil-soaked sand patties were collected from Gulf of Mexico beaches from Florida to Alabama over a three-year period from 2012 to 2014. Analysis of oil residues by gas chromatography with flame ionization detection (GC-FID), thin-layer chromatography with flame ionization detection (TLC-FID), and Fourier transform infrared spectroscopy (FT-IR) indicated uniformity in their chemical composition. Some variability within and between samples was observed, arising from differences in exposure to light and water, which increase the amount of weathering. Oxygenated hydrocarbons (OxHC) produced by weathering processes dominate the majority of oil residues. These OxHC have continued recalcitrance in the environment, and increase in relative abundance over time. Analyses of the bulk characteristics of oil residues via TLC-FID and FT-IR should be continued as these techniques provide important insight into the weathering state of oil residues.
为了研究“深水地平线”(DWH)事故所涉原油的长期风化情况,在2012年至2014年的三年时间里,从佛罗里达州到阿拉巴马州的墨西哥湾海滩收集了浸油沙饼。通过气相色谱 - 火焰离子化检测(GC - FID)、薄层色谱 - 火焰离子化检测(TLC - FID)和傅里叶变换红外光谱(FT - IR)对油残留物进行分析,结果表明其化学成分具有一致性。观察到样品内部和样品之间存在一些差异,这是由于光照和水分暴露的不同所致,而光照和水分会增加风化程度。风化过程产生的氧化烃(OxHC)在大多数油残留物中占主导地位。这些氧化烃在环境中持续具有难降解性,并且相对丰度会随时间增加。应继续通过TLC - FID和FT - IR对油残留物的整体特性进行分析,因为这些技术能为了解油残留物的风化状态提供重要见解。