State Key Lab of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology , Harbin 150080, China.
Org Lett. 2016 Nov 4;18(21):5572-5575. doi: 10.1021/acs.orglett.6b02811. Epub 2016 Oct 18.
A photoredox catalytic route to carbamates enabled by visible irradiation (or simply sunlight) has been developed. This process leads to a novel approach to the construction of heterocyclic rings wherein the amide or ester motifs of carbamates were assembled from three isolated components. Large-scale experiments were realized by employing continuous flow techniques, and reuse of photocatalyst demonstrated the green and sustainable aspects of this method.
可见光（或简单的阳光）照射下实现的光氧化还原催化合成氨基甲酸酯的方法已经被开发出来。该过程为构建杂环提供了一种新的方法，其中氨基甲酸酯的酰胺或酯基序由三个分离的组成部分组装而成。通过采用连续流动技术实现了大规模实验，并且光催化剂的重复使用证明了该方法的绿色和可持续性。
