Xia Qingchun, Liu Yan, Li Zijian, Gong Wei, Cui Yong
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China.
Chem Commun (Camb). 2016 Nov 18;52(89):13167-13170. doi: 10.1039/c6cc06019f. Epub 2016 Oct 21.
A porous Cr(salen)-MOF can serve as an efficient and effective heterogeneous catalyst for a series of important asymmetric transformations including the Nazarov cyclization, aminolysis reaction, and Diels-Alder and hetero Diels-Alder reactions, resulting in comparable or superior diastereo- or enantioselectivity with respect to the corresponding homogeneous systems.
一种多孔的Cr(salen)-金属有机框架可以作为一种高效的多相催化剂，用于一系列重要的不对称转化反应，包括纳扎罗夫环化反应、氨解反应以及狄尔斯-阿尔德反应和杂狄尔斯-阿尔德反应，相对于相应的均相体系，能产生相当或更高的非对映选择性或对映选择性。
