通过球磨法解析均配型[Ag(N,N-二芳基-NHC)]Y（Y = BF，PF）配合物的合成过程。
Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)]Y (Y = BF, PF) complexes by ball-milling.
作者信息
Beillard Audrey, Bantreil Xavier, Métro Thomas-Xavier, Martinez Jean, Lamaty Frédéric
机构信息
Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, Université de Montpellier, CNRS, ENSCM, Université de Montpellier, Campus Triolet, Place Eugène Bataillon, 34095 Montpellier cedex 5, France.
出版信息
Dalton Trans. 2016 Nov 28;45(44):17859-17866. doi: 10.1039/c6dt03564g. Epub 2016 Oct 24.
A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(i) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions.
开发了一种用户友好的通用机械化学方法，以获得具有N，N-二芳基咪唑（啉）烯配体和非配位四氟硼酸根或六氟磷酸根抗衡阴离子的罕见描述的NHC（N-杂环卡宾）银（I）配合物。与溶液中的合成方法进行比较清楚地证明了球磨条件的优越性。
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