Yuan Ruoshi, Tang Ying, Ao Ping
Key Laboratory of Systems Biomedicine, Ministry of Education, Shanghai Center for Systems Biomedicine, Shanghai Jiao Tong University, Shanghai 200240, China.
J Chem Phys. 2016 Oct 14;145(14):147104. doi: 10.1063/1.4964681.
Connections between a "SDE decomposition" to other frameworks constructing landscape in non-equilibrium processes were discussed by Zhou and Li [J. Chem. Phys. 144, 094109 (2016)]. It was speculated that the SDE decomposition would not be generally unique. In this comment, we demonstrate both mathematically and physically that the speculation is incorrect and the uniqueness is guaranteed under appropriate conditions. A few related issues are also clarified, such as the limitation of obtaining potential function from steady state distribution. Current demonstration may lead to a better understanding on the structure and robustness of the decomposition framework.
周和李[《化学物理杂志》144, 094109 (2016)]讨论了“随机动力学方程(SDE)分解”与其他在非平衡过程中构建景观的框架之间的联系。据推测,SDE分解通常不是唯一的。在本评论中,我们从数学和物理两方面证明该推测是错误的,并且在适当条件下唯一性是有保证的。还澄清了一些相关问题,例如从稳态分布获得势函数的局限性。当前的论证可能有助于更好地理解分解框架的结构和稳健性。