College of Chemistry, Sichuan University, Chengdu, 610064, Sichuan, China.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Changchun, 130022, Jilin, China.
Adv Mater. 2017 Jan;29(2). doi: 10.1002/adma.201602441. Epub 2016 Oct 31.
An Fe-doped CoP nanoarray behaves as a robust 3D monolithic multifunctional catalyst for electrolytic and hydrolytic hydrogen evolution with high activity. Its two-electrode electrolyzer needs a cell voltage of only 1.60 V for 10 mA cm water-splitting current. It also catalyzes effectively NaBH hydrolysis with a low activation energy of ≈39.6 kJ mol and a hydrogen generation rate of 6.06 L min g .
掺铁的 CoP 纳米阵列表现出作为一种高效、稳定的三维整体多功能催化剂，用于电催化和水解析氢反应。其双电极电解槽仅需 1.60 V 的电池电压即可达到 10 mA cm 的水分解电流密度。该催化剂对硼氢化钠水解也具有高效的催化作用，其活化能约为 39.6 kJ mol ，产氢速率为 6.06 L min g 。
