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用于室温下选择性捕获CO的羟基官能化超交联超微孔有机聚合物。

Hydroxy-functionalized hyper-cross-linked ultra-microporous organic polymers for selective CO capture at room temperature.

作者信息

Samanta Partha, Chandra Priyanshu, Ghosh Sujit K

机构信息

Indian Institute of Science Education and Research (IISER), Pune. Dr. Homi Bhabha Road, Pashan, Pune-411008, India. ; Tel: +91 20 2590 8076.

Indian Institute of Science Education and Research (IISER), Pune. Dr. Homi Bhabha Road, Pashan, Pune-411008, India. ; Tel: +91 20 2590 8076; Centre for Research in Energy & Sustainable Materials, IISER Pune, Pashan, Pune, India.

出版信息

Beilstein J Org Chem. 2016 Sep 2;12:1981-1986. doi: 10.3762/bjoc.12.185. eCollection 2016.

DOI:10.3762/bjoc.12.185
PMID:27829902
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5082474/
Abstract

Two hydroxy-functionalized hyper-cross-linked ultra-microporous compounds have been synthesized by Friedel-Crafts alkylation reaction and characterised with different spectroscopic techniques. Both compounds exhibit an efficient carbon dioxide uptake over other gases like N, H and O at room temperature. A high isosteric heat of adsorption () has been obtained for both materials because of strong interactions between polar -OH groups and CO molecules.

摘要

通过傅克烷基化反应合成了两种羟基官能化的超交联超微孔化合物，并用不同的光谱技术对其进行了表征。在室温下，这两种化合物对二氧化碳的吸附效率均高于氮气、氢气和氧气等其他气体。由于极性羟基基团与二氧化碳分子之间存在强相互作用，这两种材料都获得了较高的吸附等量热。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/bc090d328fb7/Beilstein_J_Org_Chem-12-1981-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/864f0ae9189c/Beilstein_J_Org_Chem-12-1981-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/0128f9ae5b0e/Beilstein_J_Org_Chem-12-1981-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/15d5ee9a487a/Beilstein_J_Org_Chem-12-1981-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/bc090d328fb7/Beilstein_J_Org_Chem-12-1981-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/864f0ae9189c/Beilstein_J_Org_Chem-12-1981-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/0128f9ae5b0e/Beilstein_J_Org_Chem-12-1981-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/15d5ee9a487a/Beilstein_J_Org_Chem-12-1981-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c959/5082474/bc090d328fb7/Beilstein_J_Org_Chem-12-1981-g004.jpg

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