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手性高价五配位磷烷

Chiral Hypervalent, Pentacoordinated Phosphoranes.

作者信息

Krasowska Dorota, Chrzanowski Jacek, Kiełbasiński Piotr, Drabowicz Józef

机构信息

Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Lodz, Poland.

Department of Chemistry, Environment Protection and Biotechnology, Jan Dlugosz University in Czestochowa, Armii Krajowej Ave. 13/15, 42-200 Czestochowa, Poland.

出版信息

Molecules. 2016 Nov 21;21(11):1573. doi: 10.3390/molecules21111573.

DOI:10.3390/molecules21111573
PMID:27879636
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6274329/
Abstract

This review presents synthetic procedures applied to the preparation of chiral (mainly optically active) pentacoordinated, hypervalent mono and bicyclic phosphoranes. The mechanisms of their stereoisomerization and their selected interconversions are also presented.

摘要

本综述介绍了用于制备手性（主要是光学活性）五配位、高价单环和双环磷烷的合成方法。还介绍了它们的立体异构化机制及其选定的相互转化。

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