在金属有机框架内控制镝金属富勒烯的磁性
Controlling the magnetic properties of dysprosium metallofullerene within metal-organic frameworks.
作者信息
Li Yongjian, Wang Taishan, Meng Haibing, Zhao Chong, Nie Mingzhe, Jiang Li, Wang Chunru
机构信息
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, 100190 Beijing, China.
出版信息
Dalton Trans. 2016 Dec 6;45(48):19226-19229. doi: 10.1039/c6dt04180a.
Magnetic endohedral metallofullerenes represent a new family of single-molecule magnets with a spherical form and solid framework. In this manuscript, we illustrate the controllable quantum tunneling of magnetism for metallofullerene DyScN@C by means of molecule encapsulation in a porous metal-organic framework (MOF-177) with strong host-guest interactions.
磁性内嵌金属富勒烯是一类新型的单分子磁体，具有球形结构和坚固的骨架。在本论文中，我们通过将金属富勒烯DyScN@C封装在具有强主客体相互作用的多孔金属有机框架（MOF-177）中，展示了其可控的磁性量子隧穿效应。
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