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避免 PCB 错误:离子液体的更可持续未来。

Avoid the PCB mistakes: A more sustainable future for ionic liquids.

机构信息

Université Savoie Mont Blanc, Laboratoire de Chimie Moléculaire et Environnement (LCME), Campus de Savoie Technolac, 73376 Le Bourget-du-Lac Cedex, France.

Université Savoie Mont Blanc, Laboratoire de Chimie Moléculaire et Environnement (LCME), Campus de Savoie Technolac, 73376 Le Bourget-du-Lac Cedex, France.

出版信息

J Hazard Mater. 2017 Feb 15;324(Pt B):773-780. doi: 10.1016/j.jhazmat.2016.11.060. Epub 2016 Nov 21.

Abstract

Based on our original knowledge and experience on both polychlorinated biphenyls (PCBs) identification in aquatic ecosystems, and use of ionic liquids (ILs) as solvents and/or co-catalysts in green chemistry, we drawn a dared comparison between these two families. Indeed, PCBs has been used during several decades for their new properties, but are now considered as prevalent and persistent pollutants; some toxic effects on environment or human are still revealed. ILs, often designated as "green solvents" are increasingly used in numerous applications, but few studies reported about their environmental impact are still controversial. Through a parallel between properties and applications of PCBs and ILs, we wondered if history could not repeat itself, and how to provide a better future for ILs. Here, we provide some interesting comparisons and we discuss which tracks it could be important to follow for ILs applications in order to avoid the errors done with PCBs.

摘要

基于我们在水生态系统中多氯联苯(PCBs)鉴定方面的原始知识和经验,以及离子液体(ILs)在绿色化学中作为溶剂和/或共催化剂的应用,我们对这两个家族进行了大胆的比较。事实上,几十年来,PCBs 因其新特性而被广泛使用,但现在被认为是普遍存在且持久的污染物;一些对环境或人类的毒性影响仍在显现。离子液体通常被指定为“绿色溶剂”,在许多应用中越来越多地被使用,但关于它们的环境影响的研究仍然存在争议。通过对 PCBs 和 ILs 的性质和应用进行平行比较,我们想知道历史是否会重演,以及如何为 ILs 的未来提供更好的前景。在这里,我们提供了一些有趣的比较,并讨论了为了避免在 PCBs 应用中犯错误,ILs 应用中哪些方面可能是重要的。

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