质子传导结晶多孔材料。
Proton-conducting crystalline porous materials.
机构信息
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, P. R. China.
College of Chemical Engineering, Shandong University of Technology, Zibo, Shandong 255049, P. R. China.
出版信息
Chem Soc Rev. 2017 Jan 23;46(2):464-480. doi: 10.1039/c6cs00528d.
Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal-organic frameworks (MOFs), coordination polymers (CPs), polyoxometalates (POMs) and covalent organic frameworks (COFs). The designable structures and high surface areas of these materials provide great opportunities to orderly accommodate proton carriers and to systemically modify the concentration and mobility of proton carriers in available spaces. Based on the understanding of the relationship between the structure and proton conductivity, controllable synthesis of porous materials with high proton conductivity will gradually be achieved. This review summarizes the emerging studies of these materials and their unique proton conductivities.
结晶多孔材料是质子传导材料领域的一个热门研究课题。结晶多孔材料包括金属-有机骨架（MOFs）、配位聚合物（CPs）、多金属氧酸盐（POMs）和共价有机骨架（COFs）。这些材料具有可设计的结构和高比表面积，为有序容纳质子载体和系统地改变可用空间中质子载体的浓度和迁移率提供了巨大的机会。基于对结构与质子电导率关系的理解，将逐步实现具有高质子电导率的多孔材料的可控合成。本综述总结了这些材料的新兴研究及其独特的质子电导率。
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