Zhou Jian, Zou Hua-Hong, Zhao Rongqing, Xiao Hong, Ding Qingran
College of chemistry, Chongqing normal university, Chongqing, 401331, P.R. China.
State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin, 541004, P.R. China.
Dalton Trans. 2017 Jan 3;46(2):342-346. doi: 10.1039/c6dt04266j.
A redox, substitution and self-assembly reaction offers a novel dysprosium selenoarsenate(iii) with As [Dy(tepa)(μ-OH)Cl][AsSe] (1, tepa = tetraethylenepentamine), which provides the first example of chair conformation ring [AsSe] combined with lanthanide complexes as counterions. 1 exhibits a photocurrent response and slow magnetic relaxation behavior.
氧化还原、取代和自组装反应产生了一种新型的三价硒代砷酸镝[Dy(tepa)(μ-OH)Cl][AsSe]（1，tepa = 四乙烯五胺），它提供了椅式构象环[AsSe]与镧系配合物作为抗衡离子结合的首个例子。1表现出光电流响应和缓慢的磁弛豫行为。
