Chen Gong-Jun, Ma Hui-Chao, Xin Wen-Ling, Li Xiao-Bo, Jin Fa-Zheng, Wang Jing-Si, Liu Ming-Yang, Dong Yu-Bin
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University , Jinan 250014, P. R. China.
Inorg Chem. 2017 Jan 3;56(1):654-660. doi: 10.1021/acs.inorgchem.6b02592. Epub 2016 Dec 15.
A new Mn(II) metal-organic framework (MOF) 1 was synthesized by the combination of 4,4,4-trifluoro-1-(4-(pyridin-4-yl)phenyl)butane-1,3-dione (L) and Mn(OAc) in solution. 1 features a threefold-interpenetrating NbO net containing honeycomb-like channels, in which the opposite Mn(II)···Mn(II) distance is 23.5075(10) Å. Furthermore, 1 can be an ideal platform to support Pd-Au bimetallic alloy nanoparticles to generate a composite catalytic system of Pd-Au@Mn(II)-MOF (2). 2 can be a highly active bifunctional heterogeneous catalyst for the one-pot tandem synthesis of imines from benzyl alcohols and anilines and from benzyl alcohols and benzylamines.
通过在溶液中将4,4,4-三氟-1-(4-(吡啶-4-基)苯基)丁烷-1,3-二酮(L)和醋酸锰相结合，合成了一种新型的锰(II)金属有机框架(MOF)1。1具有包含蜂窝状通道的三重互穿NbO网络，其中相对的锰(II)···锰(II)距离为23.5075(10) Å。此外，1可以作为一个理想的平台来负载钯-金双金属合金纳米颗粒，以生成Pd-Au@Mn(II)-MOF(2)复合催化体系。2可以作为一种高活性双功能多相催化剂，用于由苄醇和苯胺以及由苄醇和苄胺一锅串联合成亚胺。
