Zhang Long, Zhang Dechao, Yang Kun, Yan Xinlin, Wang Limin, Mi Jianli, Xu Bo, Li Yueming
State Key Laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao Hebei 066004 P.R. China.
Institute of Solid State Physics Vienna University of Technology Wiedner Hauptstr 8-10, 1040 Vienna Austria.
Adv Sci (Weinh). 2016 Apr 23;3(10):1600089. doi: 10.1002/advs.201600089. eCollection 2016 Oct.
is synthesized as a new sodium superionic conductor. The discovery of Na vacancies experimentally verifies previous theoretical predictions. Na vacancies, distorted cubic sulphur sublattices and large Na atomic displacement parameters lead to the ionic conductivity as high as 3 mS cm, a value significantly higher than those of state-of-the-art sodium sulfide electrolytes.
被合成成为一种新型的钠超离子导体。钠空位的发现通过实验验证了先前的理论预测。钠空位、扭曲的立方硫亚晶格和较大的钠原子位移参数导致离子电导率高达3 mS/cm，该值显著高于现有最先进的硫化钠电解质的电导率。
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