一系列与1,2,4-三唑和1,3,4-恶二唑衍生物相连的新型四叔丁基杯[4]芳烃的合成。
Synthesis of a Series of Novel Tetra-tert-butylcalix[4]arene Linked to 1,2,4-Triazole and 1,3,4-Oxadiazole Derivatives.
作者信息
Dono Ghezelbash Zahra, Akbari Dilmaghani Karim
出版信息
Acta Chim Slov. 2016 Dec;63(4):790-797. doi: 10.17344/acsi.2016.2637.
A series of tetra-tert-butylcalix[4]arene linked to 1,2,4-triazole-5-thiones and 1,3,4-oxadiazole-5-thiones derivatives at lower rim were synthesized by the reaction of 1,2,4-triazole-5-thione and 1,3,4-oxadiazole-5-thione with 5,11,17,23-tetra-tert-butyl-25,27-bis(3-bromopropoxy)-26,28-dihydroxycalix[4]arene (2). The synthesized compounds were characterized by FT-IR, 1H NMR, 13C NMR spectral data, elemental analysis and ESI-MS.
通过1,2,4-三唑-5-硫酮和1,3,4-恶二唑-5-硫酮与5,11,17,23-四叔丁基-25,27-双(3-溴丙氧基)-26,28-二羟基杯[4]芳烃(2)反应，合成了一系列在下缘连接有1,2,4-三唑-5-硫酮和1,3,4-恶二唑-5-硫酮衍生物的四叔丁基杯[4]芳烃。通过傅里叶变换红外光谱(FT-IR)、核磁共振氢谱(1H NMR)、核磁共振碳谱(13C NMR)光谱数据、元素分析和电喷雾电离质谱(ESI-MS)对合成的化合物进行了表征。
Zotero 插件