首个PGeP钳型亚锗烯的合成及初步过渡金属化学性质
Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.
作者信息
Álvarez-Rodríguez Lucía, Brugos Javier, Cabeza Javier A, García-Álvarez Pablo, Pérez-Carreño Enrique, Polo Diego
机构信息
Centro de Innovación en Química Avanzada (ORFEO-CINQA) and Departamento de Química Orgánica e Inorgánica-IUQOEM, Universidad de Oviedo-CSIC, E-33071 Oviedo, Spain.
出版信息
Chem Commun (Camb). 2017 Jan 16;53(5):893-896. doi: 10.1039/c6cc09283g. Epub 2016 Dec 23.
A PGeP pincer-type germylene, Ge(NCHPBu)CH, which contains two phosphane groups hanging from the N atoms of an N-heterocyclic germylene fragment, has been isolated for the first time. This compound has already furnished a rich transition metal derivative chemistry (Co, Rh, and Pd) that includes complexes containing bridging P,Ge,P-, chelating P,Ge- and pincer P,Ge,P-ligands.
一种PGeP钳型亚锗烯，即Ge(NCHPBu)CH，首次被分离出来，它含有两个从氮杂环亚锗烯片段的氮原子上悬挂的膦基团。该化合物已经展现出丰富的过渡金属衍生物化学性质（钴、铑和钯），其中包括含有桥连P,Ge,P-、螯合P,Ge-和钳型P,Ge,P-配体的配合物。
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