由脒基和亚氨基取代基支持的离域高价硅自由基。
Delocalized Hypervalent Silyl Radical Supported by Amidinate and Imino Substituents.
作者信息
Zhang Shu-Hua, Carter Emma, Xi Hong-Wei, Li Yongxin, Lim Kok Hwa, So Cheuk-Wai
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University , Singapore 637371, Singapore.
School of Chemistry, Cardiff University , Main Building, Park Place, Cardiff CF10 3AT, U.K.
出版信息
Inorg Chem. 2017 Jan 17;56(2):701-704. doi: 10.1021/acs.inorgchem.6b02427. Epub 2016 Dec 23.
The reaction of the amidinato silylsilylene with a functionalized diaminochlorosilyl substituent, [LSiSi(Cl){(NtBu)C(H)Ph}] (1; L = PhC(NtBu)), with ArN═C═NAr (Ar = 2,6-iPrCH) in toluene afforded the delocalized hypervalent silyl radical [LSi(μ-CNAr)Si{(NtBu)C(H)Ph}] (2). It possesses a hypervalent silyl radical that delocalizes throughout the SiC ring.
脒基硅硅烯与带有官能化二氨基氯硅烷基取代基的[LSiSi(Cl){(NtBu)C(H)Ph}]（1；L = PhC(NtBu)），在甲苯中与ArN═C═NAr（Ar = 2,6 - iPrCH）反应，得到离域的高价硅自由基[LSi(μ - CNAr)Si{(NtBu)C(H)Ph}]（2）。它具有一个在整个SiC环中离域的高价硅自由基。
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