Hashim Khalid S, Shaw Andy, Al Khaddar Rafid, Pedrola Montserrat Ortoneda, Phipps David
School of Civil Engineering, Liverpool John Moores University, Liverpool, UK; Department of Environment Engineering, Babylon University, Babylon, Iraq.
School of Civil Engineering, Liverpool John Moores University, Liverpool, UK.
J Environ Manage. 2017 Mar 15;189:98-108. doi: 10.1016/j.jenvman.2016.12.035. Epub 2016 Dec 21.
The goal of this project was to remove iron from drinking water using a new electrocoagulation (EC) cell. In this research, a flow column has been employed in the designing of a new electrocoagulation reactor (FCER) to achieve the planned target. Where, the water being treated flows through the perforated disc electrodes, thereby effectively mixing and aerating the water being treated. As a result, the stirring and aerating devices that until now have been widely used in the electrocoagulation reactors are unnecessary. The obtained results indicated that FCER reduced the iron concentration from 20 to 0.3 mg/L within 20 min of electrolysis at initial pH of 6, inter-electrode distance (ID) of 5 mm, current density (CD) of 1.5 mA/cm, and minimum operating cost of 0.22 US $/m. Additionally, it was found that FCER produces H gas enough to generate energy of 10.14 kW/m. Statistically, it was found that the relationship between iron removal and operating parameters could be modelled with R of 0.86, and the influence of operating parameters on iron removal followed the order: C>t>CD>pH. Finally, the SEM (scanning electron microscopy) images showed a large number of irregularities on the surface of anode due to the generation of aluminium hydroxides.
本项目的目标是使用新型电凝聚(EC)池去除饮用水中的铁。在本研究中,在设计新型电凝聚反应器(FCER)时采用了流动柱以实现预定目标。其中,待处理水通过多孔圆盘电极流动,从而有效地使待处理水混合和曝气。结果,迄今为止在电凝聚反应器中广泛使用的搅拌和曝气装置不再必要。所得结果表明,在初始pH值为6、电极间距(ID)为5毫米、电流密度(CD)为1.5毫安/平方厘米以及最低运行成本为0.22美元/立方米的条件下,FCER在电解20分钟内将铁浓度从20毫克/升降至0.3毫克/升。此外,发现FCER产生的氢气足以产生10.14千瓦/立方米的能量。从统计学角度看,发现铁去除率与运行参数之间的关系可以用相关系数R为0.86来建模,并且运行参数对铁去除率的影响顺序为:C>t>CD>pH。最后,扫描电子显微镜(SEM)图像显示,由于氢氧化铝的生成,阳极表面存在大量不规则之处。