Congener profiles, distribution, sources and ecological risk of parent and alkyl-PAHs in surface sediments of Southern Yellow Sea, China.

Congener profiles, distribution and sources of parent and alkyl-polycyclic aromatic hydrocarbons (PAHs) in surface sediments of Southern Yellow Sea (SYS), China were investigated. The ecological risk of parent-PAHs to aquatic organisms were evaluated based on sediment quality guidelines (SQGs), risk quotient (RQ), organic carbon (OC)-normalized analysis and mean effects range-median quotient (M-ERM-Q). The concentrations of 33 PAHs were analyzed, including 14 parent PAHs (without naphthalene and acenaphthylene), 16 alkyl-PAHs (7 methylphenanthrenes, 3 methylanthracenes, 3 methylfluoranthenes, and 3 methylpyrenes), dibenzothiophene, retene and perylene. Total concentrations of PAHs (TPAHs) ranged from 200.8 to 3629.0ng/g dry weight (d.w.), with a mean value of 1035.4ng/g d.w., and mainly contributed by fluorene, phenanthrene, methylphenanthrene, retene, fluoranthene and pyrene. Analysis of a broad variety of diagnostic ratios suggested that combustion was the key source of PAHs. Principal component analysis-multiple linear regression (PCA-MLR) indicated that combustion of coal, softwood and nature gas, coke oven, petroleum and vehicle emission were the main sources of PAHs in sediments of SYS, contributing 41.5%, 30.6%, 18.8%, and 9.0% to TPAHs, respectively. Ecological risk assessment of individual parent-PAHs suggested that fluorene, phenanthrene and fluoranthene may cause some risk to aquatic organisms in some stations. OC-normalized analysis and M-ERM-Q indicated that risk of multiple parent-PAHs was quite low in the studied area.