Proton-driven coordination-induced spin state switch (PD-CISSS) of iron(ii) complexes.
作者信息
Nowak René, Prasetyanto Eko Adi, De Cola Luisa, Bojer Beate, Siegel Renée, Senker Jürgen, Rössler Ernst, Weber Birgit
机构信息
Anorganische Chemie II, Universität Bayreuth, Universitätsstr. 30, NW I, 95440 Bayreuth, Germany.
出版信息
Chem Commun (Camb). 2017 Jan 16;53(5):971-974. doi: 10.1039/c6cc08618g. Epub 2017 Jan 3.
PMID:28044155
Abstract
Here we report the completely reversible spin state switch of the naturally diamagnetic tris(bipyridine)iron(ii) complex and the spin crossover complex bis(2,6-bis(1H-pyrazol-3-yl)pyridine)iron(ii) by the variation of the pH followed by H-NMR, UV-Vis spectroscopy, and magnetic and relaxivity measurements in solution and as composite materials encapsulated in a zeolite matrix.
摘要
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