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氟掺杂 α-FeO 纳米棒的合成及其对储锂性能的增强作用。

Synthesis of fluorine-doped α-FeO nanorods toward enhanced lithium storage capability.

机构信息

School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China. Department of Mechanical and Biomedical Engineering, City University of Hong Kong, Hong Kong SAR, People's Republic of China. Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR, People's Republic of China.

出版信息

Nanotechnology. 2017 Feb 10;28(6):065401. doi: 10.1088/1361-6528/aa53b3. Epub 2017 Jan 3.

Abstract

Nanostructured fluorine-doped α-FeO nanorods were synthesized based on a one-step low temperature hydrothermal method. The XPS results verified that fluorine has been successfully incorporated into the hematite lattice. The delivered lithium capacity was effectively improved owing to the fluorine doping comparing with the pristine α-FeO. The increase in electrochemical capacity of fluorine-doped α-FeO was then studied from the pointviews of nanostructure, electronic properties, and magnetic characteristics.

摘要

基于一步低温水热法合成了纳米结构的氟掺杂α-FeO 纳米棒。XPS 结果证实氟已成功掺入赤铁矿晶格中。与原始α-FeO 相比,氟掺杂有效地提高了锂的嵌入容量。然后从纳米结构、电子特性和磁特性的角度研究了氟掺杂α-FeO 电化学容量的增加。

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